Duffy and Coldplay are favourites to win Brit awards, when the annual music bash kicks off in London later.
The Welsh songstress and the stadium rockers both have four nominations and will be performing alongside Kings of Leon, Girls Aloud, Take That and U2.
The Pet Shop Boys, who receive an award for outstanding contribution, will duet with Lady GaGa to close the show.
This year's stage is themed around music festivals, with the stage adorned with caravans, ducks and tee-pees.
Gavin and Stacey stars Matthew Horne and James Corden are presenting, with help from former Brit winner Kylie Minogue.
Plant 'snubbed'
The ceremony, at London's Earls Court, comes just a week after the Grammys, where British acts dominated the main awards.
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